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The First Silver( I ) Side‐On η 2 ‐Coordination Network Formed by Self‐Assembly of Bis(pyrrol‐2‐ylmethylene)hydrazine
Author(s) -
Yang Lanying,
Shan Xufeng,
Chen Qingqi,
Wang Zhengping,
Ma Jin Shi
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300638
Subject(s) - chemistry , hydrazine (antidepressant) , pyrrole , ligand (biochemistry) , intermolecular force , hydrogen bond , coordination polymer , silver nitrate , polymer chemistry , single crystal , self assembly , crystal structure , crystallography , organic chemistry , molecule , biochemistry , receptor , chromatography
This paper reports the first silver( I ) network polymer formed by the self‐assembly of bis(pyrrol‐2‐ylmethylene)hydrazine with silver nitrate, in which the silver centers are bonded to the C−N bonds of the pyrrole rings in an η 2 ‐fashion. An X‐ray crystal structure analysis revealed that the self‐assembly of the bis(pyrrol‐2‐ylmethylene)hydrazine ligand with Ag I gives a 2D sheet, which is further assembled to form a 3D network through weak intermolecular hydrogen bonding between the protons of the pyrrole rings and the oxygen atoms of the nitrate ions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)