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Hydrothermal Synthesis and Characterization of a Novel Sinusoidal Layer Structure Constructed From Polyoxometalates and Coordination Complex Fragments
Author(s) -
Cui XiaoBing,
Xu JiQing,
Li Yong,
Sun YingHua,
Yang GuoYu
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300593
Subject(s) - polyoxometalate , chemistry , hydrothermal circulation , hydrothermal synthesis , layer (electronics) , crystallography , characterization (materials science) , hydrothermal reaction , coordination complex , layer by layer , nanotechnology , stereochemistry , chemical engineering , organic chemistry , catalysis , metal , materials science , engineering
A novel polyoxometalate compound, [As 8 V 14 O 42 (SO 4 )][Ni(en) 2 ] 3 ·4.5H 2 O ( 1 ), has been synthesized by a hydrothermal method and characterized by X‐ray crystallography, showing that the compound 1 is the first example of a sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)