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Eu III Luminescence in a Hygroscopic Ionic Liquid: Effect of Water and Evidence for a Complexation Process
Author(s) -
Billard Isabelle,
Mekki Soufiane,
Gaillard Clotilde,
Hesemann Peter,
Moutiers Gilles,
Mariet Clarisse,
Labet Alexandre,
Bünzli JeanClaude G.
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300588
Subject(s) - aqueous solution , chemistry , luminescence , coordination sphere , homogeneous , ionic radius , ionic liquid , ionic bonding , imide , ion , diffusion , metal , ligand (biochemistry) , inner sphere electron transfer , analytical chemistry (journal) , chloride , inorganic chemistry , materials science , catalysis , organic chemistry , thermodynamics , biochemistry , physics , receptor , optoelectronics
The spectroscopic characteristics (excitation, emission and lifetime) of Eu III dissolved in 1‐methyl‐3‐butylimidazolium bis(trifluoromethanesulfon)imide (BumimTf 2 N) are reported. In a first series of experiments, the effect of the presence of water in BumimTf 2 N was examined. It appears that non‐degassed solutions are most probably inhomogeneous, displaying large water clusters leading to an intense diffusion of the red light of an He:Ne laser. In these samples, the Eu emission spectrum is close to that observed in slightly acidic aqueous solutions. In contrast, when the samples were degassed the solution appeared homogeneous and water can be considered as a competitive ligand for the first coordination sphere of Eu. In a subsequent series of experiments, tetrabutylammonium chloride (TBACl) was added to the solution and the resultant species investigated. The ensuing enhancement in the metal‐centered luminescence has been interpreted in terms of changes in the inner coordination sphere of the Eu III ion and possible structures are discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)