Premium
Synthetic and Structural Studies of Pd II and Pt II Complexes with Quincorine and Quincoridine Derivatives
Author(s) -
Fild Manfred,
Thöne Carsten,
Tötös Stefania
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300557
Subject(s) - chemistry , quinuclidine , crystallography , stereochemistry , x ray crystallography , nitrogen , organic chemistry , physics , diffraction , optics
A series of Pd II ‐quincorine and ‐quincoridine complexes in which the ligands are coordinated through N , O ‐donor atoms have been synthesised, and their structural features determined by X‐ray crystallography. Additionally, new chiral tetradentate N , P ‐ligands containing two quinuclidine cores bridged through a cis ‐enediyne fragment have been obtained. The different coordinating properties of the new ligands, which contain two soft phosphorus and two hard nitrogen donors, to Pd II and Pt II are emphasised. Several typical complexes were structurally characterised by X‐ray crystallography. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)