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A Binuclear Copper( II ) Acetate Complex Showing a 3D Supramolecular Network with Hydrophilic Pockets: Its Unusual Magnetic Behaviour
Author(s) -
Fondo Matilde,
GarcíaDeibe Ana M.,
Sanmartín Jesús,
Bermejo Manuel R.,
Lezama Luis,
Rojo Teófilo
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300478
Subject(s) - chemistry , superexchange , copper , supramolecular chemistry , block (permutation group theory) , crystallography , stereochemistry , polymer chemistry , organic chemistry , ion , crystal structure , geometry , mathematics
The binuclear complex [Cu 2 L(OAc)]·6H 2 O ( 1 ) {H 3 L = 2‐(2‐hydroxyphenyl)‐1,3‐bis[4‐(2‐hydroxyphenyl)‐3‐azabut‐3‐enyl]‐1,3‐imidazolidine} which shows an unusual magnetic superexchange behaviour, acts as a building block for a novel three‐dimensional metal‐organic framework, with hydrophilic pockets. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)