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One‐ and Three‐Dimensional Coordination Polymers Containing Organic Ligands Produced Through in situ Hydrothermal Reactions
Author(s) -
Hu XiXue,
Pan ChengLing,
Xu JiQing,
Cui XiaoBing,
Yang GuangDi,
Wang TieGang
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300436
Subject(s) - chemistry , hydrothermal circulation , hydrate , hydrazine (antidepressant) , cobalt , benzene , hydrothermal reaction , in situ , polymer , coordination polymer , hydrothermal synthesis , polymer chemistry , stereochemistry , medicinal chemistry , inorganic chemistry , organic chemistry , chemical engineering , engineering , chromatography
Two novel coordination polymers of cobalt( II ), [Co(µ 3 ‐H 2 bbh)(phen)] n ( 1 ) and [Co(µ 4 ‐H 2 bbh) (H 2 O) 2 ] n ( 2 ) (phen = 1,10‐phenanthroline; H 4 bbh = benzene‐1,2,4,5‐tetracarbo‐1,2:4,5‐dihydrazide), in which H 2 bbh ligands are in situ generated by an acylation reaction of H 4 bta (H 4 bta = benzene‐1,2,4,5‐tetracarboxylic acid) with hydrazine hydrate under hydrothermal conditions have been synthesized and structurally characterized. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)