Homo‐ and Heteroleptic Hypersilylcuprates — Valuable Reagents for the Synthesis of Molecular Compounds with a Cu−Si Bond | Zendy

Klinkhammer Karl W. | Zendy; Klett Jan | Zendy; Xiong Yun | Zendy; Yao Shenglai | Zendy

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Homo‐ and Heteroleptic Hypersilylcuprates — Valuable Reagents for the Synthesis of Molecular Compounds with a Cu−Si Bond

Author(s) -

Klinkhammer Karl W.,

Klett Jan,

Xiong Yun,

Yao Shenglai

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300416

Subject(s) - chemistry , cuprate , toluene , reagent , yield (engineering) , copper , alkali metal , medicinal chemistry , inorganic chemistry , polymer chemistry , organic chemistry , superconductivity , metallurgy , physics , quantum mechanics , materials science

Unsolvated hypersilanides MHyp [Hyp = Si(SiMe 3 ) 3 ] of the heavier alkali metals (M I = Na, K, Cs) react with copper tert ‐butoxide in toluene to yield crystalline heteroleptic cuprates [M I (toluene)][ t BuOCuHyp]. These cuprates proved to be valuable sources for pure hypersilylcopper and other cuprates bearing hypersilyl ligands such as the di(hypersilyl)‐ cuprates M I [CuHyp 2 ]. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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