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The First Stable Monomeric Triaminostannane of Composition [(Me 3 Si) 3 CSn(NH t Bu) 3 ] Containing Three Substituted NH Groups
Author(s) -
Janssen Jörg,
Schmidt HansGeorg,
Noltemeyer Mathias,
Roesky Herbert W.
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300397
Subject(s) - chemistry , monomer , tin , nitrogen , composition (language) , polymer chemistry , base (topology) , primary (astronomy) , medicinal chemistry , inorganic chemistry , organic chemistry , polymer , mathematical analysis , philosophy , linguistics , physics , mathematics , astronomy
Triaminostannanes of secondary amines have been known since 1977 and are widely used in tin organic chemistry. However, the corresponding nitrogen substituted stannanes of primary amines are not cited in the literature. Herein we report on the ammonolysis reaction of [(Me 3 Si) 3 CSnCl 3 ] with t BuNH 2 in the presence of a strong base and the X‐ray structural analysis of [(Me 3 Si) 3 CSn(NH t Bu) 3 ], the first monomeric triaminostannane containing protons at the nitrogen atoms. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)