Reactivity of [Cp 2 Ti(CO) 2 ] towards Nitrile and Water Adducts of B(C 6 F 5 ) 3 : Formation of [Cp 2 Ti(η 2 ‐F 3 CC 6 H 4 CN)·B(C 6 F 5 ) 3 ] and [Cp 2 Ti][HOB(C 6 F 5 ) 3 ] with a Ti···F Interaction | Zendy

Choukroun Robert | Zendy; Lorber Christian | Zendy; Vendier Laure | Zendy

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Reactivity of [Cp 2 Ti(CO) 2 ] towards Nitrile and Water Adducts of B(C 6 F 5 ) 3 : Formation of [Cp 2 Ti(η 2 ‐F 3 CC 6 H 4 CN)·B(C 6 F 5 ) 3 ] and [Cp 2 Ti][HOB(C 6 F 5 ) 3 ] with a Ti···F Interaction

Author(s) -

Choukroun Robert,

Lorber Christian,

Vendier Laure

Publication year - 2004

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300366

Subject(s) - chemistry , adduct , borane , nitrile , reactivity (psychology) , medicinal chemistry , titanium , fluorine , stereochemistry , crystallography , catalysis , organic chemistry , medicine , alternative medicine , pathology

The reaction of [Cp 2 Ti(CO) 2 ] with borane adducts CF 3 C 6 H 4 CN·B(C 6 F 5 ) 3 and [H 2 O·B(C 6 F 5 ) 3 ] has afforded the titanaazirine [Cp 2 Ti(η 2 ‐ C , N ‐F 3 CC 6 H 4 CN)·B(C 6 F 5 ) 3 ] ( 1 ) and the Ti III salt [Cp 2 Ti][HOB(C 6 F 5 ) 3 ] ( 2 ), respectively. In both cases, a Ti ··· F interaction between the titanium centre and an ortho ‐fluorine atom of the tris(perfluorophenyl)borane is observed in the X‐ray structure determination. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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