Oxosulfido Complexes of Platinum — (Ph 3 P) 2 Pt(S 2 O) and (Ph 3 P) 4 Pt 2 (μ‐S)(μ‐SO) — Their Formation and Properties | Zendy

Ishii Akihiko | Zendy; Murata Masami | Zendy; Oshida Hideaki | Zendy; Matsumoto Kimiyo | Zendy; Nakayama Juzo | Zendy

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Oxosulfido Complexes of Platinum — (Ph 3 P) 2 Pt(S 2 O) and (Ph 3 P) 4 Pt 2 (μ‐S)(μ‐SO) — Their Formation and Properties

Author(s) -

Ishii Akihiko,

Murata Masami,

Oshida Hideaki,

Matsumoto Kimiyo,

Nakayama Juzo

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300348

Subject(s) - chemistry , platinum , oxide , inorganic chemistry , catalysis , organic chemistry

The platinum S 2 O complex [(Ph 3 P) 2 Pt(S 2 O)] ( 10 ) was obtained by S 2 O transfer reactions from tetrathiolane 2‐oxide ( 8 ), tetrathiolane 2,3‐dioxide ( 5 ), and pentathiane 3‐oxide ( 6 ) to [(C 2 H 4 )Pt(PPh 3 ) 2 ] ( 4 ). The S 2 O complex 10 further reacts with 4 to give a novel binuclear platinum complex 16 , which is found to be a source of several platinum S n O m complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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