Stepwise Assembly of Mixed Metal Dinuclear Carbonyl Complexes | Zendy

Heinze Katja | Zendy; Jacob Volker | Zendy

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Stepwise Assembly of Mixed Metal Dinuclear Carbonyl Complexes

Author(s) -

Heinze Katja,

Jacob Volker

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300272

Subject(s) - chemistry , bifunctional , isocyanide , metal , metal carbonyl , ligand (biochemistry) , bridging ligand , polymer chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , receptor

The one‐pot/three‐step solution synthesis of a library of nine directional, dinuclear mixed‐metal complexes composed of different metal‐carbonyl units (M = Cr, Mo, W) and a bifunctional bridging isocyanide Schiff‐base ligand is described. The well‐defined metal sequence in these complexes with Cr, Mo, and W in two positions can be determined post‐synthesis by a combination of spectroscopic methods. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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