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Stepwise Assembly of Mixed Metal Dinuclear Carbonyl Complexes
Author(s) -
Heinze Katja,
Jacob Volker
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300272
Subject(s) - chemistry , bifunctional , isocyanide , metal , metal carbonyl , ligand (biochemistry) , bridging ligand , polymer chemistry , stereochemistry , organic chemistry , catalysis , biochemistry , receptor
The one‐pot/three‐step solution synthesis of a library of nine directional, dinuclear mixed‐metal complexes composed of different metal‐carbonyl units (M = Cr, Mo, W) and a bifunctional bridging isocyanide Schiff‐base ligand is described. The well‐defined metal sequence in these complexes with Cr, Mo, and W in two positions can be determined post‐synthesis by a combination of spectroscopic methods. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)