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Heterometallic Molecular Squares and Polymers Based On Self‐Assembly Reactions of Multiply Bonded Dirhenium Complexes
Author(s) -
Bera Jitendra K.,
Bacsa John,
Smucker Bradley W.,
Dunbar Kim R.
Publication year - 2004
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300268
Subject(s) - chemistry , metal , ligand (biochemistry) , crystallography , polymer chemistry , polymer , self assembly , stereochemistry , organic chemistry , biochemistry , receptor
Self‐assembly reactions of the triply‐bonded dirhenium complex cis ‐[Re 2 Cl 2 (dppm) 2 (O 2 CC 5 H 4 N‐4) 2 ] with cis ‐protected Pt II and Zn II precursors have produced heterometallic squares. Analogous reactions with Ag(O 3 SCF 3 ), cis ‐[Re 2 Cl 4 (O 2 CCH 3 ) 2 (H 2 O) 2 ] and [Rh 2 (O 2 CCH 3 ) 4 ] have yielded mixed‐metal polymeric structures. These results demonstrate that the isonicotinate ligand is useful for accessing heterometallic structures involving metal−metal bonded complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)