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A Novel Tetranuclear [MeZn(μ 3 ‐OCH 2 CH 2 SMe)Zn(μ‐Cl)Me] 2 Adduct Derived from the Interaction of CH 2 Cl 2 with an Alkylzinc Complex
Author(s) -
Lewiński Janusz,
Marciniak Wojciech,
Ochal Zbigniew,
Lipkowski Janusz,
Justyniak Iwona
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300265
Subject(s) - chemistry , adduct , monomer , alcohol , chloride , zinc , ethanol , medicinal chemistry , stereochemistry , organic chemistry , polymer
The treatment of 2‐(methylthio)ethanol (methioH) with two equivalents of Me 2 Zn in CH 2 Cl 2 affords a tetranuclear aggregate with two monomeric MeZn(methio) units joined by two MeZnCl moieties. This result demonstrates that transfer of a chloride ion to Zn takes place on the addition of a donor‐functionalized alcohol to Me 2 Zn in CH 2 Cl 2 solution. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)