A Novel Tetranuclear [MeZn(μ 3 ‐OCH 2 CH 2 SMe)Zn(μ‐Cl)Me] 2  Adduct Derived from the Interaction of CH 2 Cl 2  with an Alkylzinc Complex | Zendy

Lewiński Janusz | Zendy; Marciniak Wojciech | Zendy; Ochal Zbigniew | Zendy; Lipkowski Janusz | Zendy; Justyniak Iwona | Zendy

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A Novel Tetranuclear [MeZn(μ 3 ‐OCH 2 CH 2 SMe)Zn(μ‐Cl)Me] 2 Adduct Derived from the Interaction of CH 2 Cl 2 with an Alkylzinc Complex

Author(s) -

Lewiński Janusz,

Marciniak Wojciech,

Ochal Zbigniew,

Lipkowski Janusz,

Justyniak Iwona

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300265

Subject(s) - chemistry , adduct , monomer , alcohol , chloride , zinc , ethanol , medicinal chemistry , stereochemistry , organic chemistry , polymer

The treatment of 2‐(methylthio)ethanol (methioH) with two equivalents of Me 2 Zn in CH 2 Cl 2 affords a tetranuclear aggregate with two monomeric MeZn(methio) units joined by two MeZnCl moieties. This result demonstrates that transfer of a chloride ion to Zn takes place on the addition of a donor‐functionalized alcohol to Me 2 Zn in CH 2 Cl 2 solution. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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