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Synthesis, Crystal Structure, and Optical Properties of a New Molecular Complex of C 60 with a Covalently Linked (Fe III TPP) 2 O Dimer
Author(s) -
Litvinov Aleksey L.,
Konarev Dmitri V.,
Kovalevsky Andrey Yu.,
Lapshin Alexander N.,
Yudanova Evgeniya I.,
Drichko Natalia V.,
Coppens Philip,
Lyubovskaya Rimma N.
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300256
Subject(s) - chemistry , covalent bond , van der waals force , dimer , crystallography , fullerene , tetraphenylporphyrin , molecule , electron paramagnetic resonance , crystal structure , non covalent interactions , trimer , crystal (programming language) , stereochemistry , porphyrin , photochemistry , hydrogen bond , organic chemistry , physics , nuclear magnetic resonance , computer science , programming language
A new molecular complex of C 60 with covalently linked μ‐oxo dimer (Fe III TPP) 2 O are (TPP = tetraphenylporphyrin) was obtained. The complex has a neutral ground state and is formed mainly by van der Waals forces. The X‐ray analysis of the crystal structure of the complex showed it to have isolated packing of fullerenes in which each fullerene molecule is embraced in a pocket built by porphyrins. Optical properties and EPR behavior of the complex are described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)