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The First Structurally Characterized Diorganoaluminate
Author(s) -
Eaborn Colin,
Gorrell Ian B.,
Hitchcock Peter B.,
Smith J. David
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300253
Subject(s) - chemistry , solid state , stereochemistry , crystallography , medicinal chemistry
The first structurally characterized dialkylaluminate [{Li(THF)}(Al t Bu{C(SiMe 3 ) 3 }H 2 )] 2 ( 3 ) is dimeric in the solid state with [Li(THF)] + and [Al t Bu{C(SiMe 3 ) 3 }H 2 ] − fragments linked by Li ··· H−Al bridges. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)