The First One‐Dimensional Molecular Material Featuring Maleonitriledithiolate as a Subunit Exhibiting Metamagnetic‐Like Behavior | Zendy

Xie Jingli | Zendy; Ren Xiaoming | Zendy; Gao Song | Zendy; Zhang Wenwei | Zendy; Li Yizhi | Zendy; Lu Changsheng | Zendy; Ni Chunlin | Zendy; Liu Wenlong | Zendy; Meng Qingjin | Zendy; Yao Yuangen | Zendy

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The First One‐Dimensional Molecular Material Featuring Maleonitriledithiolate as a Subunit Exhibiting Metamagnetic‐Like Behavior

Author(s) -

Xie Jingli,

Ren Xiaoming,

Gao Song,

Zhang Wenwei,

Li Yizhi,

Lu Changsheng,

Ni Chunlin,

Liu Wenlong,

Meng Qingjin,

Yao Yuangen

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200300108

Subject(s) - chemistry , antiferromagnetism , stacking , pyridinium , metamagnetism , crystallography , solid state , stereochemistry , organic chemistry , condensed matter physics , magnetization , physics , quantum mechanics , magnetic field

An ion‐pair complex [FBzPyNH 2 ][Ni(mnt) 2 ] {[FBzPyNH 2 ] + = [1‐(4′‐fluorobenzyl)‐4‐amino]pyridinium and mnt 2− = maleonitriledithiolate} has been obtained by I 2 oxidation of the corresponding dianion complex. It forms a wellsegregated stacking column structure in the solid state, and exhibits antiferromagnetic ordering below 2.5 K. It is the first complex in this series of complexes containing a maleonitriledithiolate dianion that exhibits metamagnetism. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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