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Two‐ and Three‐Dimensional Frameworks Constructed From Bicapped Keggin Clusters
Author(s) -
Duan LiMei,
Pan ChengLing,
Xu JiQing,
Cui XiaoBing,
Xie FengTong,
Wang TieGang
Publication year - 2003
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200300070
Subject(s) - chemistry , ethylenediamine , transition metal , crystallography , stereochemistry , inorganic chemistry , catalysis , organic chemistry
The novel two‐ and three‐dimensional solid materials [Cu(en) 2 (H 2 O)]{PMo VI 8 V IV 6 O 42 [Cu(en) 2 ][Cu 0.5 (en)] 3 }·5.5H 2 O and H 3 {V V Mo VI 8 V IV 6 O 42 [Cu(en) 2 ] 4 }[MoO 4 ] 2 ·14H 2 O (en = ethylenediamine) have been hydrothermally assembled and structurally characterized. Both networks are based on mixed Mo/V bicapped Keggin clusters interconnected through the transition metal complex moieties. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)