Surface Organometallic Chemistry on Oxides: The First Well‐Defined Selenium( IV ) Derivative Grafted onto Silica | Zendy

Provendier Hélène | Zendy; Santini Catherine C. | Zendy; Basset JeanMarie | Zendy; Carmona Laurent | Zendy

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Surface Organometallic Chemistry on Oxides: The First Well‐Defined Selenium( IV ) Derivative Grafted onto Silica

Author(s) -

Provendier Hélène,

Santini Catherine C.,

Basset JeanMarie,

Carmona Laurent

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200200609

Subject(s) - chemistry , fumed silica , selenium , derivative (finance) , organometallic chemistry , nuclear magnetic resonance spectroscopy , solid state , infrared spectroscopy , silica gel , inorganic chemistry , organic chemistry , polymer chemistry , catalysis , financial economics , economics

Treatment of (EtO) 2 SeO with Aerosil silica dehydroxylated at 500 °C results in the formation of a unique surface derivative [≡SiO−Se(O)OEt] ( 1 ), which has been fully characterized by elemental analysis, IR, labelling reaction and solid‐state NMR spectroscopy. This is the first example of a silica‐supported selenium( IV ) derivative. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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