Crystal Engineering with Structurally Flexible 1,1′‐Substituted Ferrocenes for Nonlinear Optical Materials | Zendy

Shin Dong Mok | Zendy; Lee In Su | Zendy; Chung Young Keun | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Crystal Engineering with Structurally Flexible 1,1′‐Substituted Ferrocenes for Nonlinear Optical Materials

Author(s) -

Shin Dong Mok,

Lee In Su,

Chung Young Keun

Publication year - 2003

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200200596

Subject(s) - chemistry , resorcinol , phloroglucinol , ferrocene , crystal engineering , quinoline , hydrogen bond , molecular engineering , crystal structure , crystallography , crystal (programming language) , stereochemistry , molecule , organic chemistry , supramolecular chemistry , electrochemistry , electrode , computer science , programming language

Cocrystals derived from 1,1′‐bis(ethenyl‐4‐pyridyl)ferrocene ( 1 ) and resorcinol/phloroglucinol and a crystal of 1,1′‐bis(ethenyl‐4‐quinolinyl)ferrocene ( 5 ) have been studied with the aim of engineering crystalline NLO materials. X‐ray structure analyses revealed a NLO active syn ‐type molecular conformation of 1 and 5 via hydrogen bonding with resorcinol/phloroglucinol and π‐π interaction between quinoline rings, respectively. For 5 , all molecular dipoles are aligned in the same direction and the SHG efficiency is about 4 times that of urea. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research