Open AccessZinc‐Based Metal–Organic Frameworks for High‐Performance Supercapacitor Electrodes: Mechanism Underlying Pore Generation
Author(s) -
Umezawa Shigeyuki,
Douura Takashi,
Yoshikawa Koji,
Tanaka Daisuke,
Stolojan Vlad,
Silva S. Ravi P.,
Yoneda Mika,
Gotoh Kazuma,
Hayashi Yasuhiko
Publication year - 2023
Publication title -
energy and environmental materials
Language(s) - English
Resource type - Journals
ISSN - 2575-0356
DOI - 10.1002/eem2.12320
Subject(s) - supercapacitor , carbonization , zinc , metal organic framework , pyrolysis , materials science , electrolyte , capacitance , carbon fibers , aqueous solution , metal , chemical engineering , electrode , electrochemistry , inorganic chemistry , chemistry , organic chemistry , metallurgy , composite material , adsorption , scanning electron microscope , composite number , engineering
Heat treatment of metal–organic frameworks (MOFs) has provided a wide variety of functional carbons coordinated with metal compounds. In this study, two kinds of zinc‐based MOF (ZMOF), C 16 H 10 O 4 Zn (ZMOF1) and C 8 H 4 O 4 Zn (ZMOF2), were prepared. ZMOF1 and ZMOF2 were carbonized at 1000 °C, forming CZMOF1 and CZMOF2, respectively. The specific surface area ( S BET ) of CZMOF2 was ~2700 m 2 g −1 , much higher than that of CZMOF1 (~1300 m 2 g −1 ). A supercapacitor electrode based on CZMOF2 achieved specific capacitances of 360, 278, and 221 F g −1 at 50, 250, and 1000 mA g −1 in an aqueous electrolyte (H 2 SO 4 ), respectively, the highest values reported to date for ZMOF‐derived electrodes under identical conditions. The practical applicability of the CZMOF‐based supercapacitor was verified in non‐aqueous electrolytes. The initial capacitance retention was 78% after 100 000 charge/discharge cycles at 10 A g −1 . Crucially, the high capacitance of CZMOF2 arises from pore generation during carbonization. Below 1000 °C, pore generation is dominated by the Zn/C ratio of ZMOFs, as carbon atoms reduce the zinc oxides formed during carbonization. Above 1000 °C, a high O/C ratio becomes essential for pore generation because the oxygen functional groups are pyrolyzed. These findings will provide insightful information for other metal‐based MOF‐derived multifunctional carbons.