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Residual Cobalt Ration during Arc Plasma Melting Treatment of Low‐Level Radioactive Wastes Containing Nickel
Author(s) -
FURUKAWA SHIZUE,
IKEDA KOUICHI,
KOTARI MASASHI,
AMAKAWA TADASHI
Publication year - 2017
Publication title -
electronics and communications in japan
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.131
H-Index - 13
eISSN - 1942-9541
pISSN - 1942-9533
DOI - 10.1002/ecj.11978
Subject(s) - materials science , cobalt , nickel , metallurgy , slag (welding) , alloy , residual , carbon fibers , metal , composite material , algorithm , composite number , computer science
SUMMARY The plasma melting treatment of low‐level radioactive waste is currently in practical use. This treatment is applied to typical radioactive wastes such as carbon steel and concrete to produce a solidified product. The scaling factor method is used to evaluate the concentration of radionuclides in the product. Because cobalt (Co) plays a particularly important role, it is important to clarify the behavior of Co during the treatment. In this report, we investigated the residual Co ratio in the slag produced during the plasma melting treatment of a nickel alloy. We found that a residual Co ratio of less than 10% was achieved in the slag when an Ni concentration of less than 80 wt% and an Fe concentration of more than 20 wt% was kept in the molten metal. The effect of the reduction of Co oxides by Fe on the residual Co ration was the most dominant among the Co oxidation/reduction reactions occurring in the molten metal.