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Analytic Properties of The OCP Ionic Mixtures in the Strongly Coupled Fluid State
Author(s) -
Dewitt Hugh E.
Publication year - 1993
Publication title -
contributions to plasma physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.531
H-Index - 47
eISSN - 1521-3986
pISSN - 0863-1042
DOI - 10.1002/ctpp.2150330511
Subject(s) - anharmonicity , coulomb , physics , limit (mathematics) , inverse , ionic bonding , function (biology) , equation of state , thermal , quantum mechanics , thermodynamics , mathematical analysis , electron , ion , mathematics , evolutionary biology , biology , geometry
Exact results for the Madelung constants and first order anharmonic energies are given for the inverse power potentials with the Coulomb potential as the softest example. Similar exact results are obtained using the analysis of Rosenfeld on the Γ →∞ limit for the OCP internal energy, direct corelation function, screening function, and bridge functions. Knowing these exact limits for the fluid phase of the OCP allows one to determine the nature of the thermal corrections to the strongly coupled results. Solutions of the HNC equation modified with the hard sphere bridge function give an example.