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Plasma phase transition (by the fiftieth anniversary of the prediction)
Author(s) -
Norman Genri E.,
Saitov Ilnur M.
Publication year - 2019
Publication title -
contributions to plasma physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.531
H-Index - 47
eISSN - 1521-3986
pISSN - 0863-1042
DOI - 10.1002/ctpp.201800182
Subject(s) - phase transition , ionization , van der waals force , ion , phase (matter) , ab initio , plasma , atomic physics , proton , hydrogen , materials science , chemical physics , physics , thermodynamics , molecule , nuclear physics , quantum mechanics
At first, we present a brief review of the problem. Then, we consider plasma phase transition (PPT) as a mechanism of the first order fluid–fluid phase transition in warm dense hydrogen. The pros and cons are analysed. The properties of warm dense hydrogen are investigated by ab initio methods of molecular dynamics using the density functional theory. Strong ionization during the fluid–fluid phase transition in warm dense hydrogen makes this transition close to the prediction of the PPT. Finally, we present differences in the real phase transition from the prediction 1968–1969. Structures are observed with inter‐proton separations that are equal to the distances between protons in theH 2 +andH 3 +ions. The transition is not only ionization, but also structural. An analysis of the phase transition counterpart in solid hydrogen under high pressure allows us to reveal partially the character of the new structure. The ionized phase includes complex cluster ions. Van der Waals loops are of abnormal inverted form.