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Versatile Chemical Recycling Strategies: Value‐Added Chemicals from Polyester and Polycarbonate Waste
Author(s) -
Payne Jack M.,
Kamran Muhammad,
Davidson Matthew G.,
Jones Matthew D.
Publication year - 2022
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202200255
Subject(s) - polyester , polycarbonate , waste management , value (mathematics) , materials science , chemistry , organic chemistry , computer science , engineering , machine learning
Abstract Zn II ‐complexes bearing half‐salan ligands were exploited in the mild and selective chemical upcycling of various commercial polyesters and polycarbonates. Remarkably, we report the first example of discrete metal‐mediated poly(bisphenol A carbonate) (BPA‐PC) methanolysis being appreciably active at room temperature. Indeed, Zn( 2 ) 2 and Zn( 2 )Et achieved complete BPA‐PC consumption within 12–18 mins in 2‐Me‐THF, noting high bisphenol A (BPA) yields ( S BPA =85–91 %) within 2–4 h. Further kinetic analysis found such catalysts to possess k app values of 0.28±0.040 and 0.47±0.049 min −1 respectively at 4 wt%, the highest reported to date. A completely circular upcycling approach to plastic waste was demonstrated through the production of several renewable poly(ester‐amide)s (PEAs), based on a terephthalamide monomer derived from bottle‐grade poly(ethylene terephthalate) (PET), which exhibited excellent thermal properties.