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Front Cover: CO 2 Chemisorption Behavior of Coordination‐Derived Phenolate Sorbents (ChemSusChem 14/2021)
Author(s) -
Suo Xian,
Yang Zhenzhen,
Fu Yuqing,
DoThanh ChiLinh,
Chen Hao,
Luo Huimin,
Jiang Deen,
Mahurin Shan M.,
Xing Huabin,
Dai Sheng
Publication year - 2021
Publication title -
chemsuschem
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202101256
Subject(s) - chemisorption , chemistry , alkali metal , benzene , inorganic chemistry , front cover , enthalpy , metal , carbonate , coordination complex , cover (algebra) , catalysis , organic chemistry , mechanical engineering , physics , quantum mechanics , engineering
The Front Cover shows the CO 2 chemisorption behavior of coordination‐derived phenolate sorbents. Phenolate‐based systems were constructed via coordination between alkali metal cations (Li + or Na + ) with crown ethers to avoid the participation of active protons in CO 2 chemisorption. CO 2 uptake could be achieved by O−C bond formation to afford carbonate. CO 2 uptake capacity and reaction enthalpy were significantly influenced by the coordination effect, alkali metal types, and alkyl groups on the benzene ring. More information can be found in the Communication by X. Suo et al.