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Alkaline Water Oxidation Using a Bimetallic Phospho‐Boride Electrocatalyst
Author(s) -
Chunduri Avani,
Gupta Suraj,
Patel Maulik,
Forster Mark,
Cowan Alexander J.,
Patel Nainesh
Publication year - 2020
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202002269
Subject(s) - overpotential , boride , bimetallic strip , electrocatalyst , oxygen evolution , water splitting , alkaline water electrolysis , electrolysis , catalysis , materials science , electron transfer , electrolysis of water , chemical engineering , inorganic chemistry , chemistry , metal , metallurgy , electrode , electrochemistry , photocatalysis , organic chemistry , engineering , electrolyte
Abstract New oxygen evolution reaction (OER) electrocatalysts based on low‐cost elements, which set new benchmark levels of activity, are vital if water electrolysis is to be applied on a global scale. Herein, a low‐cost bimetallic phospho‐boride catalyst was developed that showed outstanding OER activity of approximately 195 mV to achieve 10 mA cm −2 in alkaline water electrolysis, with a minimal catalyst loading of 0.3 mg cm −2 . The contrasting electron transfer property of the metal borides and phosphides when combined in phospho‐boride modulated the electron density of the Co atom, yielding highly active CoOOH species at lower potentials. The addition of Mo at low levels further enhanced the activity by increasing the surface area and by formation of nano‐crystalline domains. The combined contributions from each of the components resulted in a new benchmark mass activity of 666 A g −1 at 300 mV overpotential. This work presents a new avenue towards fabricating electrode materials with exceptional performances.