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Fast and Chemoselective Addition of Highly Polarized Lithium Phosphides Generated in Deep Eutectic Solvents to Aldehydes and Epoxides
Author(s) -
Cicco Luciana,
FombonaPascual Alba,
SánchezCondado Alba,
Carriedo Gabino A.,
Perna Filippo M.,
Capriati Vito,
Presa Soto Alejandro,
GarcíaÁlvarez Joaquín
Publication year - 2020
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202001869
Subject(s) - choline chloride , eutectic system , chemoselectivity , deprotonation , lithium (medication) , chemistry , ionic liquid , chloride , glycerol , deep eutectic solvent , organic chemistry , inorganic chemistry , ion , catalysis , alloy , medicine , endocrinology
The Cover Feature shows an unprecedented generation of highly polarized lithium phosphides (LiPR 2 ) through direct selective deprotonation of secondary phosphines (HPR 2 ) in the biodegradable choline chloride/glycerol eutectic mixture, at ambient temperature and under aerobic conditions, and their chemoselective addition to aldehydes or epoxides. More information can be found in the Full Paper by L. Cicco et al.