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Oxygen‐Defect‐Rich Cobalt Ferrite Nanoparticles for Practical Water Electrolysis with High Activity and Durability
Author(s) -
Debnath Bharati,
Parvin Sahanaz,
Dixit Harsha,
Bhattacharyya Sayan
Publication year - 2020
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202000932
Subject(s) - overpotential , oxygen evolution , water splitting , electrocatalyst , alkaline water electrolysis , inorganic chemistry , calcination , coprecipitation , chemical engineering , oxide , materials science , spinel , chemistry , nanoparticle , cobalt , electrolysis , cobalt oxide , catalysis , electrode , electrochemistry , electrolyte , nanotechnology , metallurgy , biochemistry , photocatalysis , engineering
The scope of any metal oxide as a catalyst for driving electrocatalytic reactions depends on its electronic structure, which is correlated to its oxygen‐defect density. Likewise, to transform a spinel oxide, such as cobalt ferrite (CoFe 2 O 4 ), into a worthy universal‐pH, bifunctional electrocatalyst for the hydrogen and oxygen evolution reactions (HER and OER, respectively), oxygen defects need to be regulated. Prepared by coprecipitation and inert calcination at 650 °C, CoFe 2 O 4 nanoparticles (NPs) require 253 and 300 mV OER overpotentials to reach current densities of 10 and 100 mA cm −2 , respectively, if nickel foam is used as a substrate. With cost‐effective carbon fiber paper, the OER overpotential increases to 372 mV at 10 mA cm −2 at pH 14. The NPs prepared at 550 °C require HER overpotentials of 218, 245, and 314 mV at −10 mA cm −2 in alkaline, acidic, and neutral pH, respectively. The intrinsic activity is reflected from turnover frequencies of >3 O 2 s −1 and >5 H 2 s −1 at overpotentials of 398 and 259 mV, respectively. If coupled for overall water splitting, the extremely durable two‐electrode electrolyzer requires a cell potential of only 1.63 V to reach 10 mA cm −2 at pH 14. The homologous couple also splits seawater at impressively low cell voltages of 1.72 and 1.47 V at room temperature and 80 °C, respectively.