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Layer‐by‐Layer Motif Heteroarchitecturing of N,S‐Codoped Reduced Graphene Oxide‐Wrapped Ni/NiS Nanoparticles for the Electrochemical Oxidation of Water
Author(s) -
Zakaria Mohamed Barakat,
Guo Yanna,
Na Jongbeom,
Tahawy Rafat,
Chikyow Toyohiro,
ElSaid Waleed A.,
ElHady Deia A.,
Alshitari Wael,
Yamauchi Yusuke,
Lin Jianjian
Publication year - 2020
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.202000159
Subject(s) - graphene , oxide , nanoparticle , electrochemistry , layer by layer , materials science , nanotechnology , layer (electronics) , chemical engineering , inorganic chemistry , chemistry , electrode , metallurgy , engineering
A new heterostructured material is synthesized with lamellar arrangements in nanoscale precision through an innovative synthetic approach. The self‐assembled Ni‐based cyano‐bridged coordination polymer flakes (Ni‐CP) and graphene oxide (GO) nanosheets with a layered morphology (Ni‐CP/GO) are used as precursors for the synthesis of multicomponent hybrid materials. Annealing of Ni‐CP/GO in nitrogen at 450 °C allows the formation of Ni 3 C/rGO nanocomposites. Grinding Ni‐CP/GO and thiourea and annealing under the same conditions produces N,S‐codoped reduced GO‐wrapped NiS 2 flakes (NiS 2 /NS‐rGO). Interestingly, further heating up to 550 °C allows the phase transformation of NiS 2 into NiS accompanied by the formation of a face‐centered cubic (FCC‐Ni) metal phase between NS‐rGO layers (FCC‐Ni‐NiS/NS‐rGO). Among all the materials, the resulting FCC‐Ni‐NiS/NS‐rGO exhibits good electrocatalytic activity and stability toward the oxygen evolution reaction (OER) owing to the synergistic effect of multiphases, the well‐designed alternating layered structures on the nanoscale with abundant active sites.