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A High‐Power Aqueous Zinc–Organic Radical Battery with Tunable Operating Voltage Triggered by Selected Anions
Author(s) -
Luo Yuwen,
Zheng Feipeng,
Liu Luojia,
Lei Kaixiang,
Hou Xuesen,
Xu Gang,
Meng Hui,
Shi Jifu,
Li Fujun
Publication year - 2020
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201903083
Subject(s) - electrochemistry , organic radical battery , chemistry , aqueous solution , redox , battery (electricity) , anode , cathode , ion , radical , inorganic chemistry , photochemistry , organic chemistry , electrode , power (physics) , physics , quantum mechanics
In contrast to traditional rechargeable rock‐chair metal‐ion batteries, dual‐ion batteries (DIBs) involve redox reactions with anions rather than cations in p‐type cathodes. In principle, regulating the electrochemical performance of the DIB by different anion species is highly feasible. Herein, the anion effect on the electrochemical performance of a DIB, the aqueous Zn– organic radical battery (Zn‐ORB), consisting of a poly(2,2,6,6tetramethylpiperidinyloxy‐4‐yl vinyl ether) cathode and a Zn anode, was investigated by DFT calculations. SO 4 2− , CF 3 SO 3 − , and ClO 4 − with different molecular electrostatic potential values were selected as anion models. DFT calculations revealed that a stronger electrostatic interaction of the anion with the organic radical resulted in a higher operating voltage of the Zn‐ORB, which was consistent with experimental results. These results bring new insight into the redox chemistry of p‐type organic radicals with anions and will promote the development of high‐power aqueous Zn‐ORBs as well as inspire more investigations into the anion effect towards novel battery designs.