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Construction of Defective Zinc–Cadmium–Sulfur Nanorods for Visible‐Light‐Driven Hydrogen Evolution Without the Use of Sacrificial Agents or Cocatalysts
Author(s) -
Zhang Guoqiang,
Ling Xiang,
Liu Guoshuai,
Xu Yangsen,
Xiao Shuning,
Zhang Qitao,
Yang Xun,
Qiu Chuntian,
Mi Hongwei,
Su Chenliang
Publication year - 2020
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201902889
Subject(s) - nanorod , photocatalysis , visible spectrum , artificial photosynthesis , hydrogen production , zinc , nanotechnology , sulfur , materials science , water splitting , reducing agent , cadmium , catalysis , chemistry , photochemistry , chemical engineering , organic chemistry , optoelectronics , metallurgy , engineering
Solar‐driven H 2 evolution is an essential process for sustainable energy development. Currently, the greatest challenge is the development of efficient photocatalysts to drive this reaction, especially in pure water systems (without the use of a sacrificial agent). In this study, structural defects in Zn–Cd–S nanorod photocatalysts are found to increase charge separation efficiency significantly by sevenfold. Efficient H 2 evolution (352.7 μmol h −1 g −1 , 100 mg of catalyst) is achieved by using this defective Zn–Cd–S nanorod photocatalyst in the absence of sacrificial agents and precious metal cocatalysts under visible‐light irradiation. Thus, this cocatalyst‐ and sacrificial‐agent‐free, visible‐light‐responsive system shows remarkable potential as a new artificial photosynthesis route for green H 2 production.