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Boosting Alkaline Hydrogen Evolution Electrocatalysis over Metallic Nickel Sites through Synergistic Coupling with Vanadium Sesquioxide
Author(s) -
Zhang Xin Yu,
Yuan Haiyang,
Mao Fangxin,
Wen Chun Fang,
Zheng Li Rong,
Liu Peng Fei,
Yang Hua Gui
Publication year - 2019
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201902599
Subject(s) - overpotential , electrocatalyst , tafel equation , nickel , alkaline water electrolysis , water splitting , vanadium , inorganic chemistry , materials science , electrolysis , catalysis , oxygen evolution , electrolysis of water , chemical engineering , transition metal , chemistry , electrochemistry , metallurgy , electrode , electrolyte , organic chemistry , photocatalysis , engineering
For renewable and sustainable energy, developing cut‐price and high‐efficiency electrocatalysts for the hydrogen evolution reaction (HER) by alkaline water electrolysis is of paramount importance. In this study, a compound electrocatalyst composed of nickel–vanadium sesquioxide nanoparticles supported on porous nickel foam (Ni‐V 2 O 3 /NF) is found to exhibit electrocatalytic performance towards HER that is superior to that of the commercial Pt/C catalyst, with nearly zero onset overpotential, an extremely low overpotential of 25 mV to obtain a current density of −10 mA cm −2 , a Tafel slope of 58 mV dec −1 , and a good durability for 24 h in 1.0 m KOH. Theoretical calculations reveal that the presence of V 2 O 3 optimizes the electronic structure of active Ni components and continuously accelerates the dissociation of water molecules, which in turn improves the HER kinetics. The present work will advance the development of highly efficient nanocomposite electrocatalysts for alkaline water electrocatalysis.