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Ultrasmall Co@Co(OH) 2 Nanoclusters Embedded in N‐Enriched Mesoporous Carbon Networks as Efficient Electrocatalysts for Water Oxidation
Author(s) -
Munir Akhtar,
ul Haq Tanveer,
Hussain Iqtidar,
Qurashi Ahsanulhaq,
Ullah Ubaid,
Iqbal Javed,
Hussain Irshad
Publication year - 2019
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201902505
Subject(s) - nanoclusters , catalysis , redox , oxygen evolution , mesoporous material , electrolyte , carbon fibers , faraday efficiency , nanotechnology , materials science , chemical engineering , electrocatalyst , metal , chemistry , inorganic chemistry , electrode , electrochemistry , organic chemistry , composite material , composite number , engineering , metallurgy
Metal nanoclusters (NCs, size ≤2 nm) are emerging materials in catalysis owing to their unique catalytic and electronic properties such as high surface/volume ratio, high redox potential, plethora of surface active sites, and dynamic behavior on a suitable support during catalysis. Herein, in situ growth of ultrasmall and robust Co@β‐Co(OH) 2 NCs (≈2 nm) hosted in a honeycomb‐like 3D N‐enriched carbon network was developed for water‐oxidation catalysis with extremely small onset potential (1.44 V). Overpotentials of 220 and 270 mV were required to achieve a current density of 10 mA cm −2 and 100 mA cm −2 , respectively, in alkaline medium (1 m KOH). More promisingly, at η 10 =240 mV, the prolonged oxygen evolution process (>130 h) with faradaic efficiency >95 % at a reaction rate of 22 s −1 at 1.46 V further substantiated the key role of the ultrasmall supported NCs, which outperformed the benchmark electrocatalysts (RuO 2 /IrO 2 ) and NCs reported so far. It is anticipated that the high redox potential of NCs with regeneratable active sites and their concerted synergistic effects with the N‐enriched porous/flexible carbon network are inherently worth considering to enhance the mass/charge transport owing to the nanoscale interfacial collaboration across the electrode/electrolyte boundary, thereby efficiently energizing the sluggish/challenging oxygen evolution process.