Ru‐Catalyzed Selective C(sp 3 )−H Monoborylation of Amides and Esters | Zendy

Yao Wubing | Zendy; Yang Jianguo | Zendy; Hao Feiyue | Zendy

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Ru‐Catalyzed Selective C(sp 3 )−H Monoborylation of Amides and Esters

Author(s) -

Yao Wubing,

Yang Jianguo,

Hao Feiyue

Publication year - 2020

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201902448

Subject(s) - borylation , ruthenium , iridium , catalysis , rhodium , chemistry , environmentally friendly , selectivity , alkyl , combinatorial chemistry , aryl , boron , organic chemistry , ecology , biology

A ruthenium‐catalyzed method has been developed for the C(sp 3 )−H monoborylation of various unactivated alkyl and aryl amides and challenging esters, with a low‐cost and bench‐stable boron source, providing boronates with exclusive selectivity, high efficiency, and high turnover number (up to 8900). This novel strategy may offer a versatile and environmentally friendly alternative to current methods for selective C(sp 3 )−H borylation that employ even more expensive metals, such as iridium and rhodium.

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