Facile Synthesis of BiVO 4  for Visible‐Light‐Induced C−C Bond Cleavage of Alkenes to Generate Carbonyls | Zendy

Han Sung Su | Zendy; Park Joon Yong | Zendy; Hwang Ho Seong | Zendy; Choe Hye Rin | Zendy; Nam Ki Min | Zendy; Cho Eun Jin | Zendy

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Facile Synthesis of BiVO 4 for Visible‐Light‐Induced C−C Bond Cleavage of Alkenes to Generate Carbonyls

Author(s) -

Han Sung Su,

Park Joon Yong,

Hwang Ho Seong,

Choe Hye Rin,

Nam Ki Min,

Cho Eun Jin

Publication year - 2019

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201900439

Subject(s) - visible spectrum , cleavage (geology) , bond cleavage , photochemistry , photocatalysis , chemistry , styrene , catalysis , oxygen , irradiation , materials science , organic chemistry , polymer , optoelectronics , copolymer , physics , fracture (geology) , nuclear physics , composite material

BiVO 4 crystals synthesized by an ultrasonic‐assisted method (Sono‐BiVO 4 ) showed improved efficiency as a heterogeneous photocatalyst under visible‐light irradiation. Sono‐BiVO 4 was successfully used for the C−C bond cleavage of alkenes to generate carbonyl compounds. Styrene derivatives were converted into carbonyl compounds in the presence of Sono‐BiVO 4 under highly sustainable conditions requiring only natural sources, that is, molecular oxygen, visible light, and water at room temperature. Additionally, Sono‐BiVO 4 could be easily separated from the reaction mixture and reused.

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