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Cobaltaelectro‐Catalyzed C−H Activation with Carbon Monoxide or Isocyanides
Author(s) -
Sau Samaresh Chandra,
Mei Ruhuai,
Struwe Julia,
Ackermann Lutz
Publication year - 2019
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201900378
Subject(s) - carbon monoxide , catalysis , cobalt , electrochemistry , chemistry , scope (computer science) , combinatorial chemistry , carbon fibers , monoxide , nanotechnology , organic chemistry , materials science , computer science , electrode , composite number , composite material , programming language
Electrochemical oxidative C−H/N−H activations with isocyanides have been realized with a versatile cobalt catalyst. The widely applicable cobalt catalysis manifold further enabled electrooxidative C−H/N−H carbonylations with carbon monoxide under ambient conditions. The C−H functionalizations were efficiently realized with ample scope and outstanding functional group tolerance in a user‐friendly undivided cell setup.
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