Selective Conversion of Cellulose to Hydroxyacetone and 1‐Hydroxy‐2‐Butanone with Sn–Ni Bimetallic Catalysts | Zendy

Wang Haiyong | Zendy; Zhu Changhui | Zendy; Liu Qiying | Zendy; Tan Jin | Zendy; Wang Chenguang | Zendy; Liang Zheng | Zendy; Ma Longlong | Zendy

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Selective Conversion of Cellulose to Hydroxyacetone and 1‐Hydroxy‐2‐Butanone with Sn–Ni Bimetallic Catalysts

Author(s) -

Wang Haiyong,

Zhu Changhui,

Liu Qiying,

Tan Jin,

Wang Chenguang,

Liang Zheng,

Ma Longlong

Publication year - 2019

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201900172

Subject(s) - hydrogenolysis , cellulose , catalysis , bimetallic strip , chemistry , cellulosic ethanol , yield (engineering) , organic chemistry , nuclear chemistry , materials science , metallurgy

The high‐value‐added chemicals hydroxyacetone (HA) and 1‐hydroxy‐2‐butanone (HB) were produced from agricultural waste over a Ni 3 Sn 4 ‐SnO x catalyst. The Sn–Ni intermetallic compound and SnO x acted as the active sites for HA and HB production by selectively cleaving the target C−C and C−O bonds. Approximately 70 % of the total HA and HB yield was obtained by selective hydrogenolysis of cellulose. This strategy expands the application of cellulose towards renewable production of high‐value C 3 and C 4 keto‐alcohols from cellulosic biomass.

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