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Mn‐Catalyzed Selective Double and Mono‐ N ‐Formylation and N ‐Methylation of Amines by using CO 2
Author(s) -
Huang Zijun,
Jiang Xiaolin,
Zhou Shaofang,
Yang Peiju,
Du ChenXia,
Li Yuehui
Publication year - 2019
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201900152
Subject(s) - formylation , chemistry , catalysis , context (archaeology) , aryl , surface modification , combinatorial chemistry , organic chemistry , alkyl , paleontology , biology
Functionalization of amines by using CO 2 is of fundamental importance considering the abundance of amines and CO 2 . In this context, the catalytic formylation and methylation of amines represent convenient and successful protocols for selective CO 2 utilization as a C 1 building block. This study represents the first example of selective catalytic double N ‐formylation of aryl amines by using a dinuclear Mn complex in the presence of phenylsilane. This robust system also allows for selective formylation and methylation of amines under a range of conditions.