Mn‐Catalyzed Selective Double and Mono‐ N ‐Formylation and  N ‐Methylation of Amines by using CO 2 | Zendy

Huang Zijun | Zendy; Jiang Xiaolin | Zendy; Zhou Shaofang | Zendy; Yang Peiju | Zendy; Du ChenXia | Zendy; Li Yuehui | Zendy

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Mn‐Catalyzed Selective Double and Mono‐ N ‐Formylation and N ‐Methylation of Amines by using CO 2

Author(s) -

Huang Zijun,

Jiang Xiaolin,

Zhou Shaofang,

Yang Peiju,

Du ChenXia,

Li Yuehui

Publication year - 2019

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201900152

Subject(s) - formylation , chemistry , catalysis , context (archaeology) , aryl , surface modification , combinatorial chemistry , organic chemistry , alkyl , paleontology , biology

Functionalization of amines by using CO 2 is of fundamental importance considering the abundance of amines and CO 2 . In this context, the catalytic formylation and methylation of amines represent convenient and successful protocols for selective CO 2 utilization as a C 1 building block. This study represents the first example of selective catalytic double N ‐formylation of aryl amines by using a dinuclear Mn complex in the presence of phenylsilane. This robust system also allows for selective formylation and methylation of amines under a range of conditions.

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