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Synthesis of MCM‐41‐Supported Metal Catalysts in Deep Eutectic Solvent for the Conversion of Carbohydrates into 5‐Hydroxymethylfurfural
Author(s) -
Feng Yunchao,
Yan Guihua,
Wang Ting,
Jia Wenlong,
Zeng Xianhai,
Sperry Jonathan,
Sun Yong,
Tang Xing,
Lei Tingzhou,
Lin Lu
Publication year - 2019
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201802792
Subject(s) - choline chloride , deep eutectic solvent , 5 hydroxymethylfurfural , chemistry , eutectic system , catalysis , solvent , aqueous solution , organic chemistry , metal , chemical engineering , inorganic chemistry , alloy , engineering
A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 was found to have excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Furthermore, the production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution (CAS; 32 wt %, relative to the reaction phase) and as a result, CAS is a more promising solvent than water and DES for HMF production.