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Efficient and Hole‐Transporting‐Layer‐Free CsPbI 2 Br Planar Heterojunction Perovskite Solar Cells through Rubidium Passivation
Author(s) -
Guo Yixin,
Zhao Fei,
Tao Jiahua,
Jiang Jinchun,
Zhang Jungang,
Yang Jianping,
Hu Zhigao,
Chu Junhao
Publication year - 2019
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201802690
Subject(s) - passivation , rubidium , materials science , perovskite (structure) , energy conversion efficiency , crystallinity , heterojunction , doping , electrode , optoelectronics , perovskite solar cell , inorganic chemistry , layer (electronics) , chemical engineering , nanotechnology , chemistry , potassium , engineering , metallurgy , composite material
Recently, inorganic perovskite CsPbI 2 Br has gained much attention for photovoltaic applications owing to its excellent thermal stability. However, low device performance and high open‐voltage loss, which are the result of its intrinsic trap states, are hindering its progress. Herein, planar CsPbI 2 Br solar cells with enhanced performance and stability were demonstrated by incorporating rubidium (Rb) cations. The Rb‐doped CsPbI 2 Br film exhibited excellent crystallinity, pinhole‐free surface morphology, and enhanced optical absorbance. By using low‐cost carbon electrodes to replace the organic hole‐transportation layer and metal electrode, an excellent efficiency of 12 % was achieved with a stabilized efficiency of over 11 % owing to the suppressed trap states and recombination in the CsPbI 2 Br film. Additionally, the annealing temperature for the Rb‐doped CsPbI 2 Br film could be as low as 150 °C with a comparable high efficiency over 11 %, which is one of the best efficiencies reported for hole‐transporting‐layer‐free all‐inorganic perovskite solar cells. These results could provide new opportunities for high‐performance and stable inorganic CsPbI 2 Br solar cells by employing A‐site cation substitution.