Multifunctional and Sustainable Fe‐Iminopyridine Complexes for the Synthesis of Cyclic Carbonates | Zendy

Seong Eun Young | Zendy; Kim Jae Hyung | Zendy; Kim Nam Hee | Zendy; Ahn KwangHyun | Zendy; Kang Eun Joo | Zendy

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Multifunctional and Sustainable Fe‐Iminopyridine Complexes for the Synthesis of Cyclic Carbonates

Author(s) -

Seong Eun Young,

Kim Jae Hyung,

Kim Nam Hee,

Ahn KwangHyun,

Kang Eun Joo

Publication year - 2019

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201802563

Subject(s) - epoxide , catalysis , halide , chemistry , ring (chemistry) , carbon dioxide , hydrogen bond , carbon fibers , photochemistry , hydrogen , organic chemistry , polymer chemistry , materials science , molecule , composite number , composite material

The use of multifunctional and sustainable Fe catalysts for the formation of cyclic carbonates from epoxides and carbon dioxide at 80 °C and 3 bar pressure is presented. The optimal catalyst possesses a halide counteranion and a hydrogen bond donor to activate the epoxide for ring opening, affording a single‐component, cocatalyst‐free catalytic system.

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