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Direct Growth of MoO 2 /Reduced Graphene Oxide Hollow Sphere Composites as Advanced Anode Materials for Potassium‐Ion Batteries
Author(s) -
Liu Cailing,
Luo Shaohua,
Huang Hongbo,
Zhai Yuchun,
Wang Zhaowen
Publication year - 2019
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201802494
Subject(s) - graphene , anode , materials science , oxide , composite number , potassium , composite material , chemical engineering , potassium ion battery , electrode , nanotechnology , chemistry , metallurgy , engineering , lithium vanadium phosphate battery
Hollow MoO 2 /reduced graphene oxide (MoO 2 /rGO) sub‐microsphere composites have been fabricated through a simple hydrothermal approach followed by a heat treatment process. When employed as an anode material for potassium‐ion batteries, the as‐synthesized MoO 2 /rGO composite can deliver an initial charge specific capacity of 367.2 mAh g −1 at 50 mA g −1 , and its reversible capacity is 218.9 mAh g −1 after 200 cycles. Even when cycled at 500 mA g −1 , a high charge specific capacity of 104.2 mAh g −1 is achieved after 500 cycles. The excellent cycling capability and rate performance may be ascribed to the synergistic effects of the reduced graphene oxide and the hollow MoO 2 spheres, which can increase the electrical conductivity of the composite, as well as resisting the strain arising from the repeated discharge–charge processes. These results indicate that the MoO 2 /rGO hollow sphere composites are promising negative electrode materials for potassium‐ion batteries.