Premium
Hierarchical Cobalt Borate/MXenes Hybrid with Extraordinary Electrocatalytic Performance in Oxygen Evolution Reaction
Author(s) -
Liu Jiapeng,
Chen Tao,
Juan Peng,
Peng Wenchao,
Li Yang,
Zhang Fengbao,
Fan Xiaobin
Publication year - 2018
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201802098
Subject(s) - tafel equation , oxygen evolution , overpotential , cobalt , mxenes , catalysis , chemistry , electrochemistry , water splitting , chemical engineering , redox , nanotechnology , materials science , inorganic chemistry , electrode , organic chemistry , photocatalysis , engineering
Abstract Oxygen evolution reaction (OER) is a key reaction for many renewable energy storage and conversion techniques. Developing efficient non‐precious metal‐based electrocatalysts for OER has attracted increasing attention. Herein is reported a strategy to fabricate hierarchical cobalt borate/Ti 3 C 2 T x MXene (Co‐B i /Ti 3 C 2 T x ) hybrid through fast chemical reactions at room temperature. This interesting hierarchical structure of Co‐B i /Ti 3 C 2 T x hybrid is beneficial for exposing more active sites, improving mass diffusion, and charge‐transfer pathways for electrochemical reaction. Moreover, a strong interaction between Co‐B i and Ti 3 C 2 T x ensures efficient charge transfer and facilitates the electrostatic attraction of more anionic intermediates for a fast redox process. Consequently, the hierarchical Co‐B i /Ti 3 C 2 T x hybrid shows extraordinary OER catalytic activity to deliver a current density of 10 mA cm −2 at an overpotential of 250 mV, and a Tafel slope of about 53 mV dec −1 .