Premium
Room‐Temperature Synthesis of Covalent Organic Framework (COF‐LZU1) Nanobars in CO 2 /Water Solvent
Author(s) -
Zhang Fanyu,
Zhang Jianling,
Zhang Bingxing,
Tan Xiuniang,
Shao Dan,
Shi Jinbiao,
Tan Dongxing,
Liu Lifei,
Feng Jiaqi,
Han Buxing,
Yang Guanying,
Zheng Lirong,
Zhang Jing
Publication year - 2018
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201801712
Subject(s) - crystallinity , covalent organic framework , solvent , covalent bond , materials science , chemical engineering , nanoscopic scale , catalysis , organic solvent , nanotechnology , organic chemistry , chemistry , composite material , engineering
The development of facile, rapid, low‐energy, environmentally benign routes for the synthesis of covalent organic frameworks (COFs) is of great interest. This study concerns the utilization of water containing dissolved CO 2 as a solvent for the room‐temperature synthesis of COF. The as‐synthesized particles, denoted COF‐LZU1, combine advantages of good crystallinity, nanoscale size, and high surface area, which suggests promising application as a support for heterogeneous catalysts. Moreover, this versatile CO 2 ‐assisted method is also applicable for the room‐temperature synthesis of Cu−COF‐LZU1. This method gives rise to new opportunities for fabricating COFs and COF‐based materials with different compositions and structures.