1,4‐Dioxane‐Tuned Catalyst‐Free Methylation of Amines by CO 2  and NaBH 4 | Zendy

Guo Zhiqiang | Zendy; Zhang Bo | Zendy; Wei Xuehong | Zendy; Xi Chanjuan | Zendy

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1,4‐Dioxane‐Tuned Catalyst‐Free Methylation of Amines by CO 2 and NaBH 4

Author(s) -

Guo Zhiqiang,

Zhang Bo,

Wei Xuehong,

Xi Chanjuan

Publication year - 2018

Publication title -

chemsuschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.412

H-Index - 157

eISSN - 1864-564X

pISSN - 1864-5631

DOI - 10.1002/cssc.201801037

Subject(s) - amine gas treating , catalysis , chemistry , surface modification , solvent , methylation , medicinal chemistry , green chemistry , combinatorial chemistry , organic chemistry , inorganic chemistry , reaction mechanism , biochemistry , gene

A catalyst‐free reductive functionalization of CO 2 with amines and NaBH 4 was developed. The N ‐methylation of amines was carried out with CO 2 as a C 1 building block and 1,4‐dioxane as the solvent. Notably, the six‐electron reduction of CO 2 to form the methyl group occurred simultaneously with formation of the C−N bond to give the N‐methylated amine.

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