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Two‐Step Synthesis of Cobalt Iron Alloy Nanoparticles Embedded in Nitrogen‐Doped Carbon Nanosheets/Carbon Nanotubes for the Oxygen Evolution Reaction
Author(s) -
Liu Yang,
Li Feng,
Yang Haidong,
Li Jing,
Ma Ping,
Zhu Yan,
Ma Jiantai
Publication year - 2018
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201800961
Subject(s) - overpotential , tafel equation , materials science , chemical engineering , carbon nanotube , electrocatalyst , catalysis , oxygen evolution , nanoparticle , carbon fibers , electrolyte , anode , cobalt , nanotechnology , inorganic chemistry , chemistry , electrochemistry , electrode , organic chemistry , composite material , metallurgy , composite number , engineering
There is a vital need to explore highly efficient and stable non‐precious‐metal catalysts for the oxygen evolution reaction (OER) to reduce the overpotential and further improve the energy‐conversion efficiency. Herein, we report a unique and cost‐effective lyophilization and thermal treatment two‐step procedure to synthesize a high‐performance hybrid consisting of CoFe alloy nanoparticles embedded in N‐doped carbon nanosheets interspersed with carbon nanotubes (CoFe‐N‐CN/CNTs) hybrid. The lyophilization step during the catalyst preparation leads to a uniform dispersion of carbon‐like precursors and avoids the agglomeration of metal particles. In addition, the inserted CNTs and doped N in this hybrid provide a good electrical conductivity, an abundance of chemically active sites, good mass transport capability, and effective gas adsorption/release channels. All these lead to a high specific surface area of 240.67 m 2 g −1 , favorable stability, and remarkable OER activities with an overpotential of only 285 mV at a current density of 10 mA cm −2 and a Tafel slope of 51.09 mV dec −1 in 1.0 m KOH electrolyte, which is even superior to commercial IrO 2 catalysts. The CoFe‐N‐CN/CNTs hybrid thus exhibits great potential as a highly efficient and earth‐abundant anode OER electrocatalyst.