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Sufficient Utilization of Zirconium Ions to Improve the Structure and Surface properties of Nickel‐Rich Cathode Materials for Lithium‐Ion Batteries
Author(s) -
He Tao,
Lu Yun,
Su Yuefeng,
Bao Liying,
Tan Jing,
Chen Lai,
Zhang Qiyu,
Li Weikang,
Chen Shi,
Wu Feng
Publication year - 2018
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201702451
Subject(s) - dopant , materials science , x ray photoelectron spectroscopy , cathode , doping , lithium (medication) , zirconium , electrochemistry , ion , thermal stability , chemical engineering , analytical chemistry (journal) , chemistry , metallurgy , electrode , optoelectronics , organic chemistry , medicine , engineering , endocrinology
We doped Zr 4+ ions in the outer layer of Ni 0.8 Co 0.1 Mn 0.1 (OH) 2 by coprecipitation. The distribution of Zr 4+ in the final cathode materials showed a gradient distribution because of ion migration during the thermal treatment. The doped layer was confirmed by using various analysis methods (energy‐dispersive X‐ray spectroscopy, XRD, X‐ray photoelectron spectroscopy, and TEM), which implies that Zr 4+ can not only occupy both the transition metal slabs and Li slabs but also form a Li 2 ZrO 3 layer on the surface as a highly ion‐conductive layer. The doped Zr 4+ in the transition metal slabs can stabilize the crystal structure because of the strong Zr−O bond energy, and the doped Zr 4+ in the Li slabs can act as pillar ions to improve the structural stability and reduce cation mixing. The gradient doping can take advantage of the “pillar effect” and restrain the “blocking effect” of the pillar ions, which reduces irreversible capacity loss and improves the cycling and rate performance of the Ni‐rich cathode materials. The capacity retention of the modified sample reached 83.2 % after 200 cycles at 1C (200 mA g −1 ) at 2.8–4.5 V, and the discharge capacity was up to 164.7 mAh g −1 at 10C. This effective strategy can improve the structure stability of the cathode material while reducing the amount of non‐electrochemical active dopant because of the gradient distribution of the dopant. In addition, the highly ion‐conductive layer of Li 2 ZrO 3 on the surface can improve the rate performance of the cathode.