Premium
Selective Electrogenerative Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandialdehyde
Author(s) -
Cao Tao,
Wu Mengjia,
Ordomsky Vitaly V.,
Xin Xi,
Wang Hao,
Métivier Pascal,
PeraTitus Marc
Publication year - 2017
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201702119
Subject(s) - 5 hydroxymethylfurfural , selectivity , catalysis , chemistry , biomass (ecology) , hydroxymethylfurfural , alcohol oxidation , organic chemistry , furfural , oceanography , geology
2,5‐furandialdehyde (DFF) was synthesized by electrogenerative oxidation of 5‐hydroxymethylfurfural (HMF) over a PtRu catalyst with 89 % selectivity at 50 °C after 17 h. This approach opens an avenue for a selective, energy‐efficient and green oxidation of biomass‐derived platform alcohols to added‐value chemicals.