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Solid Aluminum Borohydrides for Prospective Hydrogen Storage
Author(s) -
Dovgaliuk Iurii,
Safin Damir A.,
Tumanov Nikolay A.,
Morelle Fabrice,
Moulai Adel,
Černý Radovan,
Łodziana Zbigniew,
Devillers Michel,
Filinchuk Yaroslav
Publication year - 2017
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201701629
Subject(s) - hydrogen storage , borohydride , diborane , dehydrogenation , chemistry , hydrogen , inorganic chemistry , decomposition , hydride , thermal decomposition , chemical engineering , boron , organic chemistry , catalysis , engineering
Metal borohydrides are intensively researched as high‐capacity hydrogen storage materials. Aluminum is a cheap, light, and abundant element and Al 3+ can serve as a template for reversible dehydrogenation. However, Al(BH 4 ) 3 , containing 16.9 wt % of hydrogen, has a low boiling point, is explosive on air and has poor storage stability. A new family of mixed‐cation borohydrides M[Al(BH 4 ) 4 ], which are all solid under ambient conditions, show diverse thermal decomposition behaviors: Al(BH 4 ) 3 is released for M=Li + or Na + , whereas heavier derivatives evolve hydrogen and diborane. NH 4 [Al(BH 4 ) 4 ], containing both protic and hydridic hydrogen, has the lowest decomposition temperature of 35 °C and yields Al(BH 4 ) 3 ⋅NHBH and hydrogen. The decomposition temperatures, correlated with the cations’ ionic potential, show that M[Al(BH 4 ) 4 ] species are in the most practical stability window. This family of solids, with convenient and versatile properties, puts aluminum borohydride chemistry in the mainstream of hydrogen storage research, for example, for the development of reactive hydride composites with increased hydrogen content.