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New Ether‐functionalized Morpholinium‐ and Piperidinium‐based Ionic Liquids as Electrolyte Components in Lithium and Lithium–Ion Batteries
Author(s) -
Navarra Maria Assunta,
Fujimura Kanae,
Sgambetterra Mirko,
Tsurumaki Akiko,
Panero Stefania,
Nakamura Nobuhumi,
Ohno Hiroyuki,
Scrosati Bruno
Publication year - 2017
Publication title -
chemsuschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.412
H-Index - 157
eISSN - 1864-564X
pISSN - 1864-5631
DOI - 10.1002/cssc.201700346
Subject(s) - ionic liquid , electrolyte , lithium (medication) , imide , electrochemistry , chemistry , ionic conductivity , salt (chemistry) , inorganic chemistry , thermal stability , ether , conductivity , materials science , chemical engineering , polymer chemistry , organic chemistry , electrode , catalysis , medicine , engineering , endocrinology
Here, two ionic liquids, N ‐ethoxyethyl‐ N ‐methylmorpholinium bis(trifluoromethanesulfonyl)imide (M 1,2O2 TFSI) and N ‐ethoxyethyl‐ N ‐methylpiperidinium bis(trifluoromethanesulfonyl)imide (P 1,2O2 TFSI) were synthesized and compared. Fundamental relevant properties, such as thermal and electrochemical stability, density, and ionic conductivity were analyzed to evaluate the effects caused by the presence of the ether bond in the side chain and/or in the organic cation ring. Upon lithium salt addition, two electrolytes suitable for lithium batteries applications were found. Higher conducting properties of the piperidinium‐based electrolyte resulted in enhanced cycling performances when tested with LiFePO 4 (LFP) cathode in lithium cells. When mixing the P 1,2O2 TFSI/LiTFSI electrolyte with a tailored alkyl carbonate mixture, the cycling performance of both Li and Li–ion cells greatly improved, with prolonged cyclability delivering very stable capacity values, as high as the theoretical one in the case of Li/LFP cell configurations.